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Q.

In separation by fractional crystallisation method, crystallisation of which of the following compounds occurs first?

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a

compound whose melting point is highest

b

compound whose boiling point is highest

c

compound whose solubility is minimum

d

compound whose molecular weight is minimum

answer is C.

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Detailed Solution

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In fractional crystallisation, the compound with minimum solubility crystallises first, than compound with more solubility. 

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