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Q.

In SN2  reaction, the correct order of reactivity for the following compounds:
CH3Cl,CH3CH2Cl,(CH3)2CHCl ,  and  (CH3)3CCl  is 
 

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a

CH3Cl>(CH3)2CHCl>CH3CH2Cl>(CH3)3CCl

b

CH3Cl>CH3CH2Cl>(CH3)2CHCl>(CH3)3CCl

c

CH3CH2Cl>CH3Cl>(CH3)2CHCl>(CH3)3CCl

d

(CH3)3CCl>(CH3)2CHCl>CH3CH2Cl>CH3Cl

answer is B.

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Detailed Solution

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Steric hindrance around the carbon atom having cl will show down the SN2 reaction, hence lesser the hindrance, faster will be the reaction, so the order of reactivity is
CH3 CI > CH3 – CH2CI > (CH3)2 CHCI > (CH3)3 CCI 
 

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