SOCl 2 SO 2 Cl 2 x – 2 – 2 = 0 x – 4 – 2 = x – 6 = 0 x – 4 = 0 ; x = +4 x = + 6 SO 2 Cl 2 is tetrahedral because the central atom Sulphur is sp 3 hybridised and it contains no lone pair In SOCl 2 , the sulphur atom is sp 3 hybridised. Due to the presence of lone pair of electrons on the ′S′ atom, the molecule has distorted tetrahedral geometry In SOCl 2 the Cl−S−Cl and Cl−S−O bond angles are 96.5 ∘ and 107.4 ∘ respectively

The shapes of both SOCl 2 and SO 2 Cl 2 are same

The Cl–S–Cl angle in both SOCl 2 and SO 2 Cl 2 is same

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In SOCl₂ and SO₂Cl₂

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The oxidation state of sulphur is different

The hybridisation state of sulphur is same

The shapes of both SOCl₂ and SO₂Cl₂ are same

The Cl–S–Cl angle in both SOCl₂ and SO₂Cl₂ is same

answer is A, B.

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Detailed Solution

SOCl₂ SO₂Cl₂
x – 2 – 2 = 0 x – 4 – 2 = x – 6 = 0
x – 4 = 0 ; x = +4 x = + 6

SO₂Cl₂ is tetrahedral because the central atom Sulphur is sp³ hybridised and it contains no lone pair

In SOCl₂, the sulphur atom is sp³ hybridised. Due to the presence of lone pair of electrons on the ′S′ atom, the molecule has distorted tetrahedral geometry

In SOCl₂ the Cl−S−Cl and Cl−S−O bond angles are 96.5^∘ and 107.4^∘ respectively