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Q.

In sodium chloride, Cl-ions form CCParrangement. In which sites, Na+ions will occupy in this structure

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a

Tetrahedral voids

b

All octahedral voids

c

Cubic voids

d

Half of octachedral voids

answer is C.

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Detailed Solution

The Cl- ions form a CCP configuration in sodium chloride. In this structure, octahedral voids will house Na+ ions. Its coordination number will be 6. The radius ratio provides proof of this. The radius ratio for octahedral voids is rR=0.414. The ratio of the radius (r) of the atom or ion that can perfectly fit in the octahedral vacuum created by spheres of radius (R) is known as the radius ratio. rR=95181=0.524.

Hence the correct answer is C) All octahedral voids.

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