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Q.

In Sodium nitroprusside, the central metal is

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a

Fe(II)

b

Na(I)

c

Fe(III)

d

N(I)

answer is B.

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Detailed Solution

  • The odd electron of NO is transferred to Fe(III) making it Fe(II). 
  • Central atom in Sodium nitro prusside is Fe(II). 
  • It's formula is Na2[Fe(CN)5(NO)]. 
  • This is used to identify S-2 ion.
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In Sodium nitroprusside, the central metal is