Q.

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In the above reaction the major product is shown, which is formed through the intermediate (carbocation) given below: 

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Which bond will migrate to form above product ?

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a

p

b

q

c

r

d

s

answer is B.

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Detailed Solution

In the given question, option-B is correct because the intermediate is a secondary carbocation:

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If there is methyl shift from (q), then a tertiary carbocation forms along with a formation of a new six-membered ring.

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