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Q.

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In the above sequence of reactions, identify (C)

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a

Chloretone 

b

Mustard gas

c

Lewisite gas 

d

Chloropicrin

answer is C.

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Detailed Solution

Ethyl chloride on treatment with dry silver oxide forms ethanol.

Ethanol on heating with alumina to a temperature of 350oC forms ethene.

Ethene reacts with S2​Cl2 to form mustard gas (compound C).

C2​H5​Cl dry Ag2O ​C2​H5​−OH3500CAl2O3 ​CH2​=CH2S2Cl2​​Cl−CH2​−CH2​−S−CH2​−CH2​−Cl                                                                                                           

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