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Q.

In the balanced chemical reaction,

IO3- + aI- + bH+   CH2O + dI2

a, b, c and d respectively correspond to

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a

5, 6, 5, 5

b

5, 3, 6, 3

c

3, 5, 3, 6

d

5, 6, 3, 3

answer is D.

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Detailed Solution

IO3- + aI- + bH+   CH2O + dI2

OxidationReduction

I-1   I2 oxidation

2I-1   I2 

2I-1   I2 +2e----(1)

IO3-   I2 reduction

2IO3-I2

2IO3- + 12H+  I2 + 6H2O

2IO3- + 12H+ +10e-  I2 + 6H2O ---(2)

        (2)  2IO3-+10e-+12H+ I2 + 6H2O (1)×5                        10I- 5I2 +10e-                

 On addition: 2IO3-+10I-+12H+ 6I2 + 6H2O

                        IO3-+5I-+6H+3I2+3H2O

On comparing, a = 5, b = 6, c = 3, d = 3

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