Q.

In the Cannizzaro reaction given below,

2PhCHO -OH PhCH2OH+PhCO2, the slowest step is

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a

the abstraction of proton from the carboxylic acid,

b

the attack of -OH at the carbonyl group,

c

the deprotonation of PhCH2OH.

d

the transfer of hydride to the carbonyl group,

answer is B.

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Detailed Solution

The possible mechanism is
The slowest step is the transfer of hydride to the carbonyl group as shown in step (ii).

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