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Q.

In the chemical reaction, CH3CH2NH2 +CHCl3 + 3KOH (A) + (B) + 3H2O. (A) and (B) are

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a

 C2H5CN & 3KCl

b

 C2H5NC & K2CO3

c

C2H5NC & 3KCl

d

CH3CH2CO NH2 & 3KCl

answer is A.

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Detailed Solution

Given data : It is given to identify  A and B .

Explanation

The substances (A) and (B) are, respectively, C2H5NC & 3KCl.

The reaction is called the "carbylamine test" or "isocyanide test," and it involves heating aliphatic or aromatic primary amines with chloroform and alcohol potassium hydroxide to produce obnoxious-smelling alkyl isocyanides or carbylamines. This test is not performed on secondary or tertiary amines.

The chemical reaction is as follows.

CH3CH2NH2 +CHCl3 + 3KOHCH3CH2NCA+ 3KClB + 3H2O

The correct choice is (A) C2H5NC & 3KCl.

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