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Q.

In the complex, CoCl3. 3NH3, only secondary valency but not primary valency of the central metal is satisfied by

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a

Two chloride ions

b

Three chloride ions and three ammonia molecules

c

Three chloride ions

d

Three ammonia molecules

answer is D.

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Detailed Solution

According to Werner's theory, primary valency of a metal is satisfied by negative ions only.

Werner formula …CoCl3. 3NH3

Modern formula . . .Co(NH3)3Cl3

Three chloride ions satisfy both primary and secondary valency. 

Three ammonia molecules satisfy secondary valency only.

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