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Q.

In the complex, CoCl3. 5NH3, the number of ionizable chloride ions are

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a

Two

b

One 

c

Three 

d

Zero

answer is A.

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Detailed Solution

According to Werner's theory, primary valency of a metal is satisfied by negative ions only.

Werner formula …CoCl3. 5NH3

Modern formula . . .Co(NH3)5ClCl2Co(NH3)5Cl 2-+2Cl-

One chloride ion satisfies both primary and secondary valency…..dual character 

Two chloride ions satisfy primary valency only…..ionizable chloride ions

Five ammonia molecules satisfy secondary valency only.

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