Q.

In the complexes [Fe(H2O)6]3+ ,[Fe(CN)6]3,[Fe(C2O4)3]3 and [FeCl6]3, more stability is shown by

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a

[Fe(H2O)6]3+

b

[FeCl6]3

c

[Fe(CN)6]3

d

[Fe(C2O4)3]3

answer is C.

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Detailed Solution

[Fe(C2O4)3]3. The iron is present in the highest oxidation state Fe3+ and C2O42 is a chelating ligand.

Chelates are always more stable complexes

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In the complexes [Fe(H2O)6]3+ ,[Fe(CN)6]3−,[Fe(C2O4)3]3− and [FeCl6]3−, more stability is shown by