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Q.

In the curve of Freundlich adsorption equation, if the slop of the plot is zero, then extent of adsorption is

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a

inversely proportional to the pressure of gas

b

directly proportional to the pressure of gas

c

proportional to square root of the pressure of gas

d

independent of pressure of gas

answer is D.

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Detailed Solution

Freundlich gave an empirical relationship between the quantity of gas adsorbed by a unit mass of solid adsorbent and pressure at a particular temperature. The relationship can be expressed by the following equation:

x/m =k(P)1/n

where x is the mass of the gas adsorbed on mass m of the adsorbent at pressure P,,k and n are constants which depend on the nature of the adsorbent and the gas at a particular temperature.

On taking logarithm on both sides of the equation,

log(x/m​)=log(k)+1/n ​log(p)

Here,1/n is slope and if its zero then adsorption is independent of pressure as1/n ​log(p)=0

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