In the detection of sulphur present in organic compound using sodium fusion extract, the violet coloured compound formed is

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In the detection of sulphur present in organic compound using sodium fusion extract, the violet coloured compound formed is

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${[F e (S C N)]}^{2 +}$

$N a_{4} [F e {(C N)}_{5} N O S]$

${(N H_{4})}_{2} S$

$N H_{4} S C N$

answer is B.

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Detailed Solution

$S^{2 -} + \underset{N i t r o p r u s s i d e i o n}{{[F e {(C N)}_{5} N O]}^{2 -}} \to \underset{V i o l e t c o l o r}{{[F e {(C N)}_{5} N O S]}^{4 -}}$

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