Q.

In the disproportionate reaction

3HClO3HClO4+Cl2+2O2+H2O

the equivalent mass of the oxidising agent is: (molar mass) of HCIO3 = 84.45)

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a

16.89

b

32.22

c

84.45

d

28.15

answer is A.

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Detailed Solution

We know that, equivalent mass = Molar mass/oxidation number change.

Oxidation no. of Cl in HCIO. O.N. of H+O.N. of Cl+3×O.N. of O=0;+1+x+3(2)+0;x=+5

O.N. of Cl in Cl2 = 0. So, O.N. change= 5- 0 = 5 Equivalent mass = Molar mass/O.N. change = 84.45/5 i.e., 16.89
So, the correct answer is (1).

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