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Q.

In the disproportionation reaction, 3HClO3 →HClO4 + Cl2 + 2O2 + H2O, the equivalent mass of the oxidising agent is (molar mass of HClO3 = 84.45)

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a

16.89

b

32.22

c

84.45

d

28.15

answer is A.

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Detailed Solution

mathop {3HCl{O_3}}limits^{ + 5} to mathop {HCl{O_2}}limits^{ + 3} + mathop {C{l_2}}limits^0 + 2{O_2} + {H_2}O

It is a disproportion reaction. HClO3 acts like both oxidant and reductant

EW of HClO3 as oxidizing agent

mathop {HCl{O_3}}limits_{ + 5} to mathop {C{l_2}}limits_O

Decrease in O state = 5

EW of HClO3 as an oxidant =84.455= 16.89

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