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Q.

In the disproportionation reaction, 3HClO3 → HClO4 + Cl2 + 2O2 + H2O, the equivalent mass of the oxidising agent is
(molar mass of HClO3 = 84.45)

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a

16.89

b

32.22

c

84.45

d

28.15

answer is A.

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Detailed Solution

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2HCl+5O3HCl+7O4+Cl20+2O2+H2O

Here HClO3 reduces to Cl2, So it acts as an oxidizing agent.

EHClO3(as oxident)=Mchange in ox.state=84.455=16.89

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