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Q.

In the electrolysis of alumina, cryolite is added to

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a

lower the melting point of alumina 

b

 minimise the anode effect 

c

 remove impurities from alumina 
 

d

 decrease the electrical conductivity 

answer is A.

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Detailed Solution

The correct options are
1) lower the melting point of alumina.
The electrolysis of pure alumina faces some difficulties. Pure alumina is a bad conductor of electricity. The fusion temperature of pure alumina is about 2000∘C and at this temperature when electrolysis is carried out on the fused mass, the metal formed vaporizes, as the boiling point of aluminium is 1800∘C. These difficulties are overcome by using a mixture containing alumina, cryolite (Na3,AlF6), and fluorspar (CaF2,). But the addition of cryolite do not minimize the anode effect and do not remove the impurities from alumina.
 

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