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Q.

In the electrolysis of aqueous NaCl solution, side reactions taking place are:

(I) 2OH+Cl2Cl-+OCl+H2O

(II) 2Na+2H2O2NaOH+H2

(III) 4OHO2+2H2+4e

Select the correct alternate :

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a

(I) and (II)

b

 (II) and (III) 

c

(I). (II), and (III) 

answer is D.

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Detailed Solution

aqueous NaCl has ions H+ ,Na+, OH--, Cl--

chlorine formed reacts with base and shows disproportionation

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In the electrolysis of aqueous NaCl solution, side reactions taking place are:(I) 2OH−+Cl2⟶Cl-+OCl−+H2O(II) 2Na+2H2O⟶2NaOH+H2(III) 4OH−⟶O2+2H2+4e−Select the correct alternate :