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Q.

In the extraction of chlorine from brine

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a

Gofor the overall reaction is negative

b

Gofor the overall reaction is positive

c

Eofor the. overall reaction has negative value

d

Eofor the overall reaction has positive value

answer is B.

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Detailed Solution

Electrolysis of brine solution is used to extract chlorine. Overall chemical reaction occurring in this process and value of Go can be shown as
2H2O(l)+2Cl(aq)H2(g)+Cl2(g)+2OH(aq)
For the given reaction, value of ΔG is +422 kJ
Using ΔG=nFEc the value of E=2.2V.
Therefore,ΔGfor the overall reaction is positive and Eohas negative value.

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