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Q.

In the following balanced reaction, 

XMnO4+YC2O42+ZH+ XMn2++2YCO2+Z2H2O
values of X, Y and Z respectively are 

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a

5,8,4

b

8,2,5 

c

5,2,16 

d

2,5,16 

answer is A.

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Detailed Solution

XMnO4+YC2O4+ZH+XMn+++2YCO2+Z2H2O
First half reaction 
MnO4Mn++         ...(i)

On balancing 
MnO4+8H++5eMn+++4H2O     ...(ii)
Second half reaction 
C2O42CO2        .....(iii)
On balancing 
C2O42CO2+2e       ....(iv)
On balancing 
C2O42CO2+2e           ...(iv)
On multiplying eqn. (ii) by 5 and (iv) by 2 and then adding we get 
2MnO4+5C2O4+16H+ 2Mn+++10CO2+8H2O

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