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In the following compound, arrange the reactivity of different bromine atoms towards NaSH in decreasing order :

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$P > S > Q > R$

$P > Q > R > S$

$S > Q > P > R$

$Q > S > P > R$

answer is C.

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Detailed Solution

The reactivity order with SH- , follows given order, Q>S>P>R, since

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Towards sN2. The ‘BR’ indicated by R is at bridge –head so has least ease to undergo this reaction.

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