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Q.

In the following compounds some undergo disproportion with conc. NaOH and some do not give disproportionation with  conc.NaOH
 F2,Cl2,Br2,NO2,CH3COCH3,CCl3CHO,P4,I2,(CH3)2CHCHO,HCHO.
‘x’ are the number of compound which undergo dispropotionation and ‘y’ are the number of compound which do not undergo dispropotionation , Then value of 3x/y is ____ 
 

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answer is 7.

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Detailed Solution

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3Cl2+6NaOH(conc.)5NaCl+NaclO3+H2O          3Br2+6NaOH(conc.)5NaBr+NaBrO3+3H2O       3l2+6NaOH(conc.)5Nal+NalO3+3H2O          3H2O+P4+Conc.3NaOHPH3+3NaH2PO2          (CH3)2CHCHO+Conc.NaOH(CH3)2CHCOONa++(CH3)2CHCH2OH       HCHO+Conc.NaOHHCOONa+CH3OH

Total 6 compound undergo disproportionation.
So  x=6&y=5x/y=1.2

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