In the following compounds some undergo disproportion with conc. NaOH and some do not give disproportionation with $c o n c . N a O H$ .
$F_{2}, C l_{2}, B r_{2}, N O_{2}, C H_{3} C O C H_{3}, C C l_{3} C H O, P_{4}, I_{2}, {(C H_{3})}_{2} C H C H O, H C H O .$
‘x’ are the number of compound which undergo dispropotionation and ‘y’ are the number of compound which do not undergo dispropotionation , Then value of 3x/y is ____

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answer is 7.

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Detailed Solution

$3 C l_{2} + 6 N a O H (c o n c .) \to 5 N a C l + N a c l O_{3} + H_{2} O 3 B r_{2} + 6 N a O H (c o n c .) \to 5 N a B r + N a B r O_{3} + 3 H_{2} O 3 l_{2} + 6 N a O H (c o n c .) \to 5 N a l + N a l O_{3} + 3 H_{2} O 3 H_{2} O + P_{4} + C o n c .3 N a O H \to P H_{3} + 3 N a H_{2} P O_{2} {(C H_{3})}_{2} C H C H O + C o n c . N a O H \to {(C H_{3})}_{2} C H C O O^{-} N a^{+} + {(C H_{3})}_{2} C H C H_{2} O H H C H O + C o n c . N a O H \Rightarrow H C O O^{-} N a^{+} C H_{3} O H$