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Q.

In the following observation.

AcidKa1Ka2(X)
Oxalic acid5.9×10-26.4×10-5 
Ascorbic acid7.4×10-41.6×10-12 
Sulphurous acid1.7×10-26.4×10-8 
(Y)Very large1.2×10-2 
Carbonic acid4.3×10-7(Z) 
Citric acid7.4×10-41.7×10-54.0×10-7
Phosphoric acid7.5×10-36.2×10-84.2×10-13

X,Y and Z respectively are

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a

Ka3, phosphorous acid, 6.5×10-11

b

Ka3, sulphuric acid, 5.6×10-11

c

K=Ka1×Ka2, phosphorous acid, 6.5×10-11

d

K=Ka1×Ka2, sulphuric acid, 5.6×10-11

answer is D.

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Detailed Solution

The X ,Y and Z are Ka3, sulphuric acid and 5.6×10-11, respectively.

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