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Q.

In the following reaction :

3Fe+4H2OFe3O4+4H2, if the atomic weight of iron is 56, then iron equivalent weight in Fe3O4 its equivalent weight will be

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a

42

b

63

c

21

d

84

answer is B.

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Detailed Solution

Fe3O4 is an Oxide. Oxidation state of Oxygen in Oxides is -2. So, total Oxidation state of four Oxygens is -8.

It implies that total Oxidation state of three Irons in Fe3O4is +8. 

3 Iron atoms from zero O.S. got changed to +8 by the loss of 8 electrons.

Equivalent weight of Iron in Fe3O4=Mass of all Iron atoms 56×3Total number of e-1 lost by them 8=21

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