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Q.

In the following reaction: Carbonyl compound +MeOH⇌HClacetal, rate of the reaction is higher for

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a

acetone as substrate and methanol in excess

b

Propanal as substrate and methanol in stoichiometric amount

c

Propanal as substrate and methanol in excess

d

Acetone as substrate and methanol in stiochiometric amount

answer is C.

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Detailed Solution

Generally, aldehydes are more reactive than ketone in nucleophillic addition reactions. Rate of reaction with alcohol to form acetal and ketal is
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