Q.

In the following reaction ‘X’ is  CH3(CH2)4CH3HClΔAhy  AlCl3'X'Major  product

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a

ClCH2(CH2)4CH2Cl

b

CH3(CH2)4CH2Cl

c

CH3CH|CH3(CH2)2CH3

d

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answer is C.

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Detailed Solution

n-alkanes on heating in this presence of anhydrous  and hydrogens chloride gas isomerise to branched  Chain alkanes. The major product has one methyl side chain
 CH3(CH2)4CH3HClΔAhy  AlCl3CH3CH |CH3(CH2)2CH3
  2-methylpentane(major)
 

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In the following reaction ‘X’ is  CH3(CH2)4CH3→HCl ΔAhy  AlCl3'X'Major  product