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Q.

In the following reaction, AgCl+KIKCl+AgI As KI is added, the equilibrium is shifted towards right giving more AgI precipitate, because

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a

Both AgCl and AgI are sparingly soluble

b

The KSp of AgI is lower than KSp of AgCl

c

The KSpof Ag I is higher than KSp of AgCl

d

Both AgCl and AgI have same solubility product

answer is B.

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Detailed Solution

AgCl+KIKCl+AgI

KSpof AgI is lower than KSP of AgCl 

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In the following reaction, AgCl+KI⇌KCl+AgI As KI is added, the equilibrium is shifted towards right giving more AgI precipitate, because