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In the following reactions which is deuterolysis
I) ${AlCl}_{3} + 3 D_{2} O \to Al {(OD)}_{3} + 3 DCl$
II) ${CaC}_{2} + 2 D_{2} O \to Ca {(OD)}_{2} + C_{2} D_{2}$
III) ${Mg}_{3} P_{2} + 6 D_{2} O \to 3 Mg {(OD)}_{2} + 2 {PD}_{3}$

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I and II only

II and III only

I and III only

I, II and III

answer is D.

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Detailed Solution

Deuterolysis reactions: The reactions in which a salt reacts with heavy water to give a base and an acid.

${AlCl}_{3} + 3 D_{2} O \to Al {(OD)}_{3} + 3 DCl$

${CaC}_{2} + 2 D_{2} O \to Ca {(OD)}_{2} + C_{2} D_{2}$

${Mg}_{3} P_{2} + 6 D_{2} O \to 3 Mg {(OD)}_{2} + 2 {PD}_{3}$

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