Q.

In the following reaction, SO2 acts as a reducing agent :

SO2+Cl2+2H2OH2SO4+3HCl

Find the equivalent weight of SO2.

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answer is 32.

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Detailed Solution

SO2+Cl2+2H2OH2SO4+3HCl n.f=2

S changes oxidation state from + 4 to +6

 Equivalent weight = Molecular weight  Total change in oxidation number 

 Eq wt. of SO2= mol. wt of SO22=642=32g

Thus, the correct answer is 32.

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