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Q.

In the following reaction

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The % yield for reaction I is 60% and that of reaction II is 50%. The overall yield of the complete reaction is ___% [nearest integer]

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answer is 30.

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Detailed Solution

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(I)

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Let initial moles of reactant taken = n

Total moles obtained for benzene sulphonic acid (with % yield = 60%) = 0.6n

(II)

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Moles of benzene sulphonic acid before reaction II = 0.6n

Moles obtained for phenol (with % yield = 50%) = 0.6 × 0.5 n =0.3 n

So over all % yield of complete reaction=0.3nn×100=30

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