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Q.

In the following sequence of reaction, the final product (Z) is

HCCHH2SO4Hg+2 X H2OCH3MgX Y [O] Z

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a

ethanol 

b

propanol

c

propan-2-ol 

d

propanone 

answer is C.

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Detailed Solution

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When we treat ethyne with Hg+2/H2SO4 then product is acetaldehyde(X) after this when we treat X with CH3MgX/H2O then propanal(Y) formed at last on oxidation we will get propanone(Z).

 HCCH Hg+2/H2SO4 CH3CHOCH3MgX/H2O  CH3-CH(OH)-CH3 (O)CH3-CO-CH3

Therefore, correct option is: (C) propanone.

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In the following sequence of reaction, the final product (Z) isHC≡CH→H2SO4Hg+2 X →H2OCH3MgX Y →[O] Z