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Q.

In the following sequence of reactions

CH3BrKCNAH3O+BLiAlH4, The end product C is

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a

Methane

b

Acetone

c

Acetaldehyde

d

Ethyl alcohol

answer is B.

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Detailed Solution

The reaction,

CH3BrKCNCH3-CANH3O+CH3-COOHBLiAlH4CH3-CH2-OH

Acetonitrile is created when methyl bromide and KCN react with each other. CN group is used to replace the Br atom. Cyano group hydrolysis produces a carboxylic group. Hydroxyl group is produced when a carboxylic group is reduced.

Hence, the correct answer is option (B) Ethyl alcohol.

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In the following sequence of reactionsCH3Br⟶KCNA⟶H3O+B⟶LiAlH4, The end product C is