Q.

In the following sub questions choose the correct answer from among the following possibilities and express the final answer as sum of the numbers
(P) The most stable low valent halide  (1) GeX2 (2) SnX2 (3) PbX2
(Q) A non existing halide  (1) SnCl4 (2) PbCl4 (3) PbI4
(R) A purely acidic oxide  (1) PbO2 (2) SnO2 (3) SiO2
(S) Thermally most stable hydride  (1) NH3(2)PH3 (3) AsH3

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answer is 10.

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Detailed Solution

P) In a group the tendency to exhibit inert pair effect increase downwards = 3
Q) PbI4: because of more polarazability of I it act as reducing agent= 3
R) SiO2: PbO2 and SnO2 are amphoteric in nature=3
S) NH3: In VA group hydrides the M-H bond energy decrease down words the group
and thermal stability decreases = 1
 3+3+3+1=10

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