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Q.

In the following the correct bond order sequence is:

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a

O22->O2+>O2->O2

b

O2+>O2->O22->O2

c

O2>O2->O22->O2+

d

O2+>O2>O2->O22->

answer is D.

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Detailed Solution

 

O2=(σ1s2)(σ1s*2)(σ2s2)(σ2s*2)(σ2pz2)(π2px2=π2py2)(π2px*1=π2py*1) bond order=(bonding-antibonding)2=10-62=2

Now as the electron on the atom increases bond order decreases.

The bond order of the following is: O22-=10-82=1; O2-=10-72=1.5; O2=2; O2+=10-52=2.5

Hence, the correct option is: (D)O2+>O2>O2->O22-

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