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Q.

In the formation of hydrides of  Vth and  VIth group elements, only in the hydride of  1st member the central atom involves in sp3 hybridization but in other atoms the central atom undergo only partial hybridization or only pure orbitals participate in bonding. This is because

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a

In N and O   the hybrid orbitals are small in size and can overlap effectively compared to pure orbitals with s-orbital of hydrogen atoms

b

In the heavier members ofN  andO  families the hybrid orbitals are larger and cannot overlap effectively compared to pure orbitals with s-orbital of hydrogen atoms

c

Compared to the pure p-orbital, the electron distribution in s-orbitals is much more diffuse than inspn  hybrids or p-orbitals alone

d

Hybridization of orbitals of an atom takes place only in the atoms of 2nd  period elements

answer is A, B, C.

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Detailed Solution

Due to hybridization the size of orbitals change Electron distribution in s-orbitals is much more diffuse than inspn   hybrids or p-orbitals alone. The hybridization of 3s and 3p orbitals on sulphur or phosphorous would produce more favorable bond angles with regard to repulsion, but the overlap between those orbitals and the hydrogen 1s orbitals is less effective. The hydrogen orbitals can overlap better with a smaller unhybridized p-orbital on sulphur or phosphorous . The result is that the orbitals used by the central atom have a very slight degree of hybridization but closely resemble pure p-orbitals

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In the formation of hydrides of  Vth and  VIth group elements, only in the hydride of  1st member the central atom involves in sp3 hybridization but in other atoms the central atom undergo only partial hybridization or only pure orbitals participate in bonding. This is because