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Q.

In the given reaction, 
           2Cu+(aq)Cu2+(aq)+Cu(s)ECu+/Cu=0.6V and ECu2+/Cu=0.41V
Find out the equilibrium constant.

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a

2.76×108

b

2.76×102

c

2.76×104

d

2.76×106

answer is C.

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Detailed Solution

Right hand cell reaction, Cu++eCu
Left hand cell reaction, Cu+Cu2++e
Cell reactions, 2Cu+Cu+Cu2+
Cell potential Ecell =ECu+/CuECu2+/C
                           =0.600.41=0.19V nFE=RTlnKeqlogKeq=nE(2.303RT/F)=2×0.19V0.059V=6.44        Keq=106.44=2.76×106

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