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Q.

In the ionic compound,AB the ratio rA+ : rB−is 0.414 Indicate the correct statement of the following:

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a

Anions form close packing and cations occupy precisely half of the tetrahedral voids

b

Anions form close packing and cations fit into the octahedral voids loosely

c

Anions form close packing and cations occupy precisely all the octahedral voids

d

Cations form close packing and anions exactly fit into the octahedral voids

answer is C.

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Detailed Solution

Range of octahedral void is 0.414 - 0.732. Larger the size of anion lesser is the ratio and larger unit occupy corners and smaller unit occupy  void

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