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Q.

In the isolation of fluorine a number of difficulties were encountered. Which statements are incorrect?

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a

Fluorine has great affinity for hydrogen

b

The potential required for the discharge of the fluoride ions lowest

c

Electrolysis of aqueous HF gives ozonized oxygen

d

Fluorine reacts with moist glass vessels

answer is A, B, C.

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Detailed Solution

1. Fluorine reacts with water and glass vessels.
Thus, option A is incorrect.

2. Fluorine has great affinity for hydrogen. It reacts with hydrogen with an explosion even in dark.
However, this was not the difficulty encountered in the extraction of fluorine.
Thus, option B is incorrect.

3. The electrolysis of aqueous HF gives oxygen and not ozonized oxygen.
Thus, option C is also incorrect.

4. The potential required for the discharge of the fluoride ions is lowest.
Thus, option D is also correct.

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