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Q.

In the Kjeldal’s estimation of nitrogen in the form of NH3  small amounts of K2SO4 is added to the system.

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a

To provide common ion effect for dissociation of CuSO4

b

Here K2SO4 acts as a catalyst

c

K2SO4 raises the boiling point of H2SO4

d

K2SO4is responsible for converting NH3 to NH42SO4

answer is D.

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Detailed Solution

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Kjeldahl's method is used for the estimation of nitrogen. The organic compound is heated with conc. H2​SO4​ in presence of K2​SO4​ and a little CuSO4​ to convert all the nitrogen into (NH4​)2​SO4​⋅K2​SO4​ raises the boiling point of H2​SO4​ while CuSO4​ catalyzes the reaction.

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