Q.

In the leaching method, bauxite ore is digested with a concentrated solution of NaOH that produces 'X'. When CO2 gas is passed through the aqueous solution of 'X', a hydrated compound 'Y' is precipitated. ‘X’ and 'Y' respectively are. 

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a

NaAl(OH)4 and Al2O3xH2O

b

NaAl(OH)4 and Al2CO33xH2O

c

NaAlO2 and Al2CO33xH2O

d

Al(OH)3 and Al2O3xH2O

answer is D.

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Detailed Solution

Al2O3(s)Alumina+2NaOH(aq)+3H2O(l) 35-36 bar473523K2NaAl(OH)4(aq)Sodium aluminate(X)
2NaAl(OH)4(aq)+CO2(g)Al2O3xH2O(s)Hydrated alumina(Y)+2NaHCO3(aq)

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