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Q.

 In the preparation of HBr or HI, NaX (X : Br, I) is treated with H3PO4 and not by concentrated H2SO4 since

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a

Na3PO4 is water insoluble and Na2SO4 is water soluble 

b

Na2SO4 is water soluble and Na3PO4 is water insoluble 

c

H2SO4 oxidizes HX to X2Br2,I2

d

H2SO4 makes the reaction reversible 

answer is C.

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Detailed Solution

HBr or HI cannot be prepared by heating Br or I with conc. H2SO4 because HBr and HI are strong reducing agents and reduces 

H2SO4 to SO2 and Br or I are oxidized to Br2 or I2

respectively. 

NaX+H2SO4NaHSO4+HXH2SO4+2HXSO2+X2+2H2O(X=Br or I)

Hence HBr and HI are prepared by heating  Br and I respectively with H3PO4

3NaBr+H3PO4Na3PO4+3HBr3NaI+H3PO4Na3PO4+3HI

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