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In the reaction 2PCl₅ $⇌$ PCl₄⁺ + PCl₆^– the change in hybridization is from

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sp³d to sp³ and sp³d²

sp³d to sp² and sp³

sp³d to sp³d² and sp³d³

sp³d² to sp³ and sp³d

answer is A.

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Detailed Solution

Number of electron pairs =

V = Group number of central atom

M = Number of monovalent groups directly attached to central atom

C = overall positive charge of the species

A = Overall negative charge of the species.

Number of bond pairs = Number of atoms directly attached to central atom

"Bond Pairs" according to VSEPR theory can be single bond, double b and (or) triple bond

Number of lone pairs = (Number of electron pairs-Number of bond pairs)

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