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Q.

In the reaction  2SO2(g)+O2(g)2SO3(g),ΔH<0  The yield of SO3(g) is increased when

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a

temperature is increased keeping pressure constant

b

temperature is decreased and pressure is increased

c

both temperature and pressure are increased

d

both temperature and pressure are decreased

answer is B.

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Detailed Solution

In the reaction  2SO2(g)+O2(g)2SO3(g),ΔH<0  The yield of SO3(g) is increased when temperature is decreased and pressure is increased

Sulfur trioxide takes a very long time to develop at low temperatures. Elevating the temperature accelerates the process of reaching equilibrium. On the other hand, a high-temperature results in a lower percentage yield of sulphur trioxide.
The side with the lesser gas volume benefits from an increase in pressure. In the process described above, sulphur dioxide and oxygen combine to generate sulphur trioxide.

Hence option B is correct

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