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Q.

In the reaction between Cl2 and hot conc. NaOH, which is correct:

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a

The oxidation number of Cl2 changes from 0 to +5 and 0 to-1

b

Cl2 undergoes disproportionation

c

Cl2 undergoes self or auto redox change

d

All of these

answer is D.

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Detailed Solution

With hot concentrated alkali solutions it forms chlorates.
6NaOH+3Cl2​→5NaCl+NaClO3​+3H2​O
                0           -1       +5                             
Cl2 undergoes disproportionation.

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