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Q.

In the reaction FeC2O4 → Fe3+ + 2CO2, the equivalent mass FeC2O4 is

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a

its molar mass

b

molar mass3

c

molar mass4

d

Molar mass ×2

answer is B.

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Detailed Solution

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large left. {begin{array}{*{20}{c}} {mathop {F{e^{ + 2}}}limits_{ + 2} ; to ;mathop {F{e^{ + 3}}}limits_{ + 3} } \ {Increase;in;Ox.state; = ;1} \ {Total;increase;in;Ox.State; = ;1} end{array}} right|begin{array}{*{20}{c}} {mathop {{C_2}O_4^{ - 2}}limits_{ + 3} ; to ;mathop {2C{O_2}}limits_{ + 4} } \ {Increase;in;Ox.state; = ;1} \ {Total;increase;in;Ox.state; = ;2 times 1 = 2} end{array}


Total increase in Oxidation number mole of FeC2O4 = 3
 

large therefore EW;of;FeC_2O_4;=;frac{MW}{3}

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In the reaction FeC2O4 → Fe3+ + 2CO2, the equivalent mass FeC2O4 is