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In the reaction $\large 2S{O_{3\left( g \right)\,}},\, \rightleftharpoons \,2S{O_{2\left( g \right)}}\, + \,{O_{2\left( g \right)}},\,\,S{O_{3\left( g \right)}}$ is 50% dissociated at 27⁰C when the equilibrium pressure is 0.5 atm. Partial pressure of SO_3(g) at Equilibrium is

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a

0.5 atm

b

0.3 atm

c

0.2 atm

d

0.1 atm

answer is C.

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Detailed Solution

	2 SO_3(g)	$⇌$	2SO_2(g) + O_2(g)
Initial moles	1		0 0
Moles at equilibrium	1-0.5=0.5		0.5 0.25

Total moles at equilibrium =0.5 +0.5 0.25 = 1.25

Partial pressure of SO₃ at equilibrium = $χ_{{SO}_{3}} \times P =$ $\frac{0.5}{1.25} \times 0.5$ =0.2 atm

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In the reaction is 50% dissociated at 270C when the equilibrium pressure is 0.5 atm. Partial pressure of SO3(g) at Equilibrium is