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Q.

In the reaction of sodium thiosulphate with l2 in aqueous medium, the equivalent weight of sodium thiosulphate is equal to

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a

Molar mass of sodium thiosulphate

b

The average of molar masses of Na2S2O3 and I2

c

Half the molar mass of sodium thiosulphate

d

Molar mass of sodium thiosulphate x 2

answer is A.

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Detailed Solution

2Na2S2O3 + I2  2NaI + Na2S4O6

Equivalent weight is the molecular weight divided by number of electrons lost or gained by each molecule.

Half reactions occur as:
I2 + 2e-2I- 2S2O32S4O62+2e
2 electrons are lost by 2 molecules of  S2​O32−(Sodium thiosulphate). So, one molecule will lose 1 electron. So, equivalent weight is equal to molecular weight divided by 1.

Equivalent weight of Na2S2O3
= Mol.wt. 1=2481=248

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