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Q.

In the reaction 2NaOH+H3PO4Na2HPO4+2H2O, the Equivalent weight of the acid is

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a

36.5

b

32.6

c

49

d

98

answer is A.

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Detailed Solution

We are required to calculate the Equivalent weight of H3PO4.

2NaOH+H3PO4Na2HPO4+2H2O

In the reaction

The number of hydrogen ions replaced by the base of acid is 2.

The molar mass of the acid= 98 g

Now we know that equivalent weight=Molecular WeightNet positive valence

Therefore, the Equivalent weight of H3PO4=982=49

Hence, option(a) is correct.

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